The noun is derived from Old English wana; the verb from Old English wanian via Middle English wanien. Both ultimately trace to Proto-West Germanic *wanōn, from Proto-Germanic *wanōną, from Proto-Indo-European *h₁weh₂- ("to leave, abandon; empty, deserted").
See also wan-, want, and waste. Compare also Dutch waan ("insanity") and German Wahn ("insanity") deprecated defect, Old Norse vanr ("lacking") ( > Danish prefix van-, only found in compounds), Latin vanus, Gothic 𐍅𐌰𐌽𐍃 ("missing, lacking"), Albanian vonë ("late, futile, mentally retarded"), Armenian ունայն ("empty"), Old Saxon and Old High German wanon ("to decrease"), Modern Dutch weinig ("a few"), Modern German weniger ("less"), comparative of wenig (-ig being a derivate suffix; -er the suffix of comparatives). vain, vaunt, vaniloquent, vast, vacuum, vacant, vacate, which are Latin-derived, via the PIE root.
From Scots wean.
From Middle English wone, wane, of unclear origins, compare wont.
Modern English dictionary
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